L(+)-Arabinose Basic information |
Product Name: | L(+)-Arabinose |
Synonyms: | ARABITOL, L-(-)-(RG);L-ARABINOSE extrapure;(2R,3R,4S,5S)-oxane-2,3,4,5-tetrol;L-Arabinose 98%;L-(+)-Arabinose, L-arabinose;L-Arabinopyranose;l-[1-13C]arabinose;l-[2-13C]arabinose |
CAS: | 87-72-9 |
MF: | C5H10O5 |
MW: | 150.13 |
EINECS: | 201-767-6 |
Product Categories: | Sugars, Carbohydrates & Glucosides;Inhibitors;Dextrins,Sugar & Carbohydrates;Carbohydrates & Derivatives;carbohydrate;Food Additives |
Mol File: | 87-72-9.mol |
L(+)-Arabinose Chemical Properties |
Melting point | 160-163 °C(lit.) |
alpha | 103 º (c=5, H2O) |
Boiling point | 191.65°C (rough estimate) |
density | 1.1897 (rough estimate) |
refractive index | 1.3920 (estimate) |
storage temp. | Store at RT. |
pka | 12.26±0.70(Predicted) |
form | Fine Crystalline Powder |
color | White |
Water Solubility | soluble |
Merck | 14,761 |
BRN | 1723085 |
CAS DataBase Reference | 87-72-9(CAS DataBase Reference) |
NIST Chemistry Reference | Arabinose(L)(87-72-9) |
EPA Substance Registry System | L-Arabinopyranose (87-72-9) |
Safety Information |
Hazard Codes | Xn |
Risk Statements | 20/21/22-36/37/38 |
Safety Statements | 24/25-36-26 |
WGK Germany | 3 |
F | 3-10 |
TSCA | Yes |
HS Code | 29400000 |
MSDS Information |
Provider | Language |
---|---|
L-Arabinopyranose | English |
ACROS | English |
ALFA | English |
L(+)-Arabinose Usage And Synthesis |
Chemical Properties | White to off white crystalline powder |
Uses | A base component of hemicellulose and pectin, critical biopolymers. |
Purification Methods | beta-L-(+)-Arabinose is recrystallised slowly, twice, from 80% aqueous EtOH, then dried under vacuum over P2O5. It can also be purified by heating the arabinose (200g) with glacial acetic acid (300mL) on a boiling water bath for 45minutes, cooling, filtering, washing with 95% EtOH (500mL) in four portions and drying at 56-60o over P2O5. It has been recrystallised from 5times its weight of 76% EtOH using charcoal (10g) to yield 127g, m 155-157o, [] 20D +190.6o and mutarotating to +104o (c 4, H2O). [Anderson & Sands Org Synth Coll Vol I 67 1941, Wolfrom & Christian J Am Chem Soc 48 3172 1926, Beilstein 1 IV 4217.] |
L(+)-Arabinose Preparation Products And Raw materials |