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Dibenzyl disulfide Basic information |
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Dibenzyl disulfide Chemical Properties |
Hazard Codes |
Xi |
Risk Statements |
43 |
Safety Statements |
22-36/37-37-24 |
WGK Germany |
2 |
RTECS |
JO1750000 |
TSCA |
Yes |
HS Code |
29309090 |
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Dibenzyl disulfide Usage And Synthesis |
Chemical Properties |
White Solid |
Chemical Properties |
Benzyl disulfide has a powerful, burnt-caramel odor; irritating when concentrated. |
Uses |
Originating from Petiveria alliacea L. This compound along with the other sulfur-containing compound found in this plant display antibacterial and antifungal activity. |
Uses |
Antioxidant in rubber compounding, stabilizer for petroleum fractions, additive to silicone oils. The soly in oils is increased by the presence of benzyl alcohol. |
Definition |
ChEBI: An organic disulfide that results from the formal oxidative dimerisation of benzyl thiol. |
Preparation |
From benzyl chloride and Na2S2; also from benzyl mercaptan via oxidation. |
Synthesis Reference(s) |
The Journal of Organic Chemistry, 54, p. 2998, 1989 DOI: 10.1021/jo00274a002
Synthetic Communications, 22, p. 3277, 1992 DOI: 10.1080/00397919208021143
Tetrahedron Letters, 31, p. 5007, 1990 DOI: 10.1016/S0040-4039(00)97790-6 |
Purification Methods |
Crystallise the disulfide from EtOH (m 77o), pet r or CS2 (m 72o) or distil it. The AgNO3 complex has m 103o. [Beilstein 6 H 465, 6 I 229, 6 II 437, 6 III 1635, 6 IV 2760.] |
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Dibenzyl disulfide Preparation Products And Raw materials |
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