L-ABRINE Basic information |
|
L-ABRINE Chemical Properties |
Melting point |
>300 °C (dec.) (lit.) |
alpha |
D21 +44° (0.28 g in 10 ml 0.5N HCl) |
Boiling point |
358.94°C (rough estimate) |
density |
1.272±0.06 g/cm3 (20 ºC 760 Torr) |
refractive index |
65 ° (C=1, 0.5mol/L NaOH) |
pKa |
2.32±0.10(Predicted) |
optical activity |
[α]20/D +65°, c = 1 in 0.5 M NaOH |
Merck |
14,10 |
BRN |
86638 |
CAS DataBase Reference |
526-31-8(CAS DataBase Reference) |
Hazard Codes |
Xn |
Risk Statements |
20/21/22 |
Safety Statements |
36 |
WGK Germany |
3 |
HS Code |
29339900 |
|
L-ABRINE Usage And Synthesis |
Chemical Properties |
white to light grey crystalline powder or crystals |
Definition |
ChEBI: A N-methyl-L-alpha-amino acid that is the Nalpha-methyl derivative of L-tryptophan. |
Purification Methods |
Crystallise L-abrine from H2O or EtOH/H2O mixture and dry it for 2days at 60o in high vacuum; it has m 275-290o(dec with browning at 230o) and [] D +47.2o (c 2, 0.5N HCl) [Peter et al. Helv Chim Acta 46 577 1963]. [Gregory & Morley J Chem Soc 913 1968, Beilstein 22/14 V 40.] |
|
L-ABRINE Preparation Products And Raw materials |
|
|
|
|